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New 2D spectroscopy methods

6 July 2018 | News
by Ian Michael

Physicists and chemists at the Julius-Maximilians-Universität Würzburg (JMU) in Germany have published two novel principles of optical spectroscopy in the Nature Communications. Both approaches show new developments of coherent two-dimensional (2D) spectroscopy. In conventional 2D spectroscopy, scientists excite a system at a specific frequency and observe what happens at another frequency.

“Instead of starting with one excitation and analysing its dynamics, we here deploy two excitations into the same system and observe how they interact”, says Professor Brixner, who is in charge of the research project at the University of Würzburg. This gives direct access, for example, to propagation phenomena (such as energy transport) because signals in the new method arise only if two initially separated excitations move and then meet.

The scientists illustrate the idea of “exciton-exciton-interaction-two-dimensional-(EEI2D)-spectroscopy” using a perylene bisimide-based J-aggregate. “J-aggregates are among the most important classes of supramolecular structures and the class of perylene bisimide dyes is ideally suited for such experiments”, Professor Frank Würthner explains.

This method is applicable to numerous physical, chemical, biological or engineering systems, for example, to decode dynamic properties such as energy transport of natural light-harvesting systems and artificial dye aggregates.

The physicists in Tobias Brixner’s team conducted further research by combining coherent 2D spectroscopy with molecular beams. “This has allowed us to investigate ionisation with the 2D scheme for the first time”, he explains. For this purpose, they used mass spectrometry instead of optical detection and obtained 2D spectra not only for the parent molecule but, simultaneously, also for all photoproducts.

“Our main challenge was the fact that particle densities in molecular beams are very low, rendering futile any previous conventional attempts at detecting coherently emitted four-wave-mixing signals”, Brixner says. Instead, the researchers observed the ion generated by the sequence of excitation pulses, thereby merging two hitherto separate fields of research, namely 2D spectroscopy and mass spectrometry.

The physicists used the method as an example to identify the ionisation pathways of 3d Rydberg states in nitrogen dioxide. In the future, this development will allow studying the influence of the environment on the coherent dynamics in larger molecules.

Both new approaches were developed within the scope of the research projects “Solar Technologies Go Hybrid” of DFG Research Unit 1809 and the ERC project “MULTISCOPE”.

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